Diaryl Sulfates as Electrophiles in Kumada Cross-Coupling
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doi:10.1055/s-0029-1219595

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Synfacts 2010(4): 0455-0455
DOI: 10.1055/s-0029-1219595

Metal-Mediated Synthesis

Diaryl Sulfates as Electrophiles in Kumada Cross-Coupling Reactions

Contributor(s): Paul Knochel, Andreas J. Wagner
B.-T. Guan, X.-Y. Lu, Y. Zheng, D.-G. Yu, T. Wu, K.-L. Li, B.-J. Li, Z.-J. Shi*
Peking University and Shanghai Institute of Organic Chemistry, P. R. of China

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Publication History

Publication Date:
22 March 2010 (online)

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Significance

Diaryl sulfates were successfully used as electrophiles in nickel-catalyzed Kumada cross-couplings. The reaction affords unsymmetrical biaryls in high yields. The only byproducts are harmless inorganic salts.